O-bearing complex organic molecules at the cyanopolyyne peak of TMC-1: Detection of C₂H₃CHO, C₂H₃OH, HCOOCH₃, and CH₃OCH₃

We report the detection of oxygen-bearing complex organic molecules propenal (C2H3CHO), vinyl alcohol (C2H3OH), methyl formate (HCOOCH3), and dimethyl ether (CH3OCH3) toward cyanopolyyne peak starless core TMC-1. These are detected through several emission lines in a deep Q-band line survey TMC-1 carried out with Yebes 40m telescope. observations reveal that TMC-1, which is prototype cold dark cloud rich carbon chains, contains also O-bearing like HCOOCH3 CH3OCH3, have been previously seen handful interstellar clouds. In addition, this first secure C2H3OH space time C2H3CHO environment, adding new pieces puzzle sources. derive column densities (2.2 +/- 0.3)e11 cm-2, (2.5 0.5)e12 (1.1 0.2)e12 0.7)e12 cm-2 for C2H3CHO, C2H3OH, HCOOCH3, respectively. Interestingly, has an abundance similar to its well known isomer acetaldehyde (CH3CHO), C2H3OH/CH3CHO ~ 1 at peak. discuss potential formation routes these recognize further experimental, theoretical, astronomical studies needed elucidate true mechanism